Reaction of carbon dioxide with a palladium-alkyl complex supported by a bis-NHC framework.

نویسندگان

  • Piyal W G Ariyananda
  • Glenn P A Yap
  • Joel Rosenthal
چکیده

The reactivity of a dimethyl palladium complex supported by a dicarbene chelate (MDC(Mes))PdMe(2) towards CO(2) has been investigated. In the presence of trace H(2)O, this reaction yields the corresponding methyl bicarbonate complex (MDC(Mes))PdMe(O(2)COH), which goes on to give the corresponding κ(2)-carbonato complex upon crystallization (MDC(Mes))Pd(CO(3)). This chemistry, as well as related protonolysis by acetic acid was monitored by a combination of techniques including React-IR spectroscopy.

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عنوان ژورنال:
  • Dalton transactions

دوره 41 26  شماره 

صفحات  -

تاریخ انتشار 2012